Method of operating fuel cell with high power and high power fuel cell system

ABSTRACT

A fuel cell is operated with high power such that which a humidified gas and a dry gas are selectively supplied as oxidant to a cathode of the fuel cell. This method includes (S1) supplying a humidified gas while a power is constantly maintained or until the power begins to decrease; (S2) after supplying the humidified gas, supplying a dry gas to obtain a greater power than an average power of the step (S1); and (S3) after obtaining a predetermined power in the step (S2), repeatedly supplying a humidified gas in case the power decreases and supplying a dry gas in case the power decreases again afterwards, thereby increasing the power such that the predetermined power is maintained. This method provides an optimal operating condition to a fuel cell, thereby ensuring a high power.

TECHNICAL FIELD

The present invention relates to a method of operating a fuel cell withhigh power and a high power fuel cell system. More particularly, thepresent invention relates to a method of operating a fuel cell with highpower and a high power fuel cell system, which prevents flooding andmaintains an amount of moisture in an electrode to an optimal state.

BACKGROUND ART

Recently, as depletion of conventional energy resources such as oil orcoal is foreseen, interest in alternative energies is increasing. A fuelcell is one of the alternative energies, and advantageously has a highefficiency, does not emit pollutants such as NO_(x) and SO_(x) and usesa fuel that is abundant in quantity, and therefore, the fuel cellattracts public attention.

The fuel cell is a power generation system that converts chemicalreaction energy of a fuel and an oxidant to electrical energy, andtypically hydrogen and hydrocarbon, for example methanol or butane, areused as a fuel, and oxygen is representatively used as an oxidant.

In the fuel cell, a membrane electrode assembly (MEA) is the basic unitfor generating electricity, and includes an electrolyte membrane andanode and cathode electrodes formed at opposite sides of the electrolytemembrane. FIG. 1 illustrates the principle for generating electricity ofa fuel cell, and Chemical FIG. 1 represents a reaction formula of a fuelcell in the case that hydrogen is used as a fuel. Referring to FIG. 1and Chemistry FIG. 1, an oxidation reaction of a fuel occurs at an anodeelectrode to generate hydrogen ions and electrons, and the hydrogen ionsmove to a cathode electrode through an electrolyte membrane. Thehydrogen ions transmitted through the electrolyte membrane and theelectrons react with oxygen (oxidant) at the cathode electrode togenerate water. This reaction causes the electrons to move to anexternal circuit.

Chemistry FIG. 1

Anode electrode: H₂→2H⁺+2e⁻

cathode electrode: ½O₂+2H⁺+2e⁻→H₂O

Reaction formula: H₂+½O₂→H₂O

FIG. 2 illustrates a general configuration of a membrane electrodeassembly for a fuel cell. Referring to FIG. 2, a membrane electrodeassembly for a fuel cell includes an electrolyte membrane 201, and ananode electrode and a cathode electrode located at opposite sides of theelectrolyte membrane 201. The anode and cathode electrodes respectivelyinclude catalyst layers 203, 205 and a gas diffusion layer 208. The gasdiffusion layer includes electrode substrates 209 a, 209 b andmicroporous layers 207 a, 207 b formed on the electrode substrates.

Studies for a fuel cell exhibiting a high power required to enhancecompatibility of a fuel cell with many advantages as mentioned abovebecome more active, and particularly the demands on fuel cells capableof continuously providing high power are more increased.

A fuel cell generates electricity by moving hydrogen ions as mentionedabove. Here, what is helpful for moving such hydrogen ions is moisture,which is also a resultant of reaction in the electrode. However, theamount of moisture generated as a result of reaction is not sosufficient to fully ensure ion conductivity of a fuel cell, so a fuelcell is generally operated under a humidity condition.

However, if there exists an excessive amount of moisture, floodingoccurs, which may block fine holes in a catalyst layer or a gasdiffusion layer, decrease a three-phase reaction point, and decrease theefficiency of a fuel cell resultantly.

As mentioned above, the amount of moisture in an electrode of a fuelcell is a factor dominating the performance of the electrode. Thus, inorder to obtain a high power from a fuel cell, moisture introduced intoan electrode or generated from the electrode should be suitablycontrolled.

However, such control is very troublesome, and no effective solution hasbeen suggested up to now. Thus, it is urgent to develop a techniquecapable of maintaining a suitable amount of moisture in an electrode ofa fuel cell to obtain a high power.

DISCLOSURE Technical Problem

Therefore, an object of the present invention is to provide a method ofoperating a fuel cell and a fuel cell system, which may enhance a powerof the fuel cell by controlling the flooding phenomenon withoutsupplying additional fuel or oxidant.

Technical Solution

In order to accomplish the above object, the present invention providesa method of operating a fuel cell with high power, in which a humidifiedgas and a dry gas are selectively supplied as oxidant to a cathode ofthe fuel cell, the method including: (S1) supplying a humidified gaswhile a power is constantly maintained or until the power begins todecrease; (S2) after supplying the humidified gas, supplying a dry gasto obtain a greater power than an average power of the step (S1); and(S3) after obtaining a predetermined power in the step (S2), repeatedlysupplying a humidified gas in case the power decreases and supplying adry gas in case the power decreases again afterwards, thereby increasingthe power such that the predetermined power is maintained.

Inventors found that the power of a fuel cell is greatly improved when adry gas is supplied while a humidified gas is supplied for a certaintime. The inventors also found that the improved power is maintainedwhen a humidified gas and a dry gas are alternately supplied afterwards.Thus, the method of operating a fuel cell according to the presentinvention enables to give a high power from a fuel cell.

In the above method, the fuel cell is preferably operated with currentdensity of 500 mA/cm² or above. Also, in the steps (S1) and (S3), thehumidified gas is preferably supplied for 20 seconds or less, and, inthe steps (S2) and (S3), the dry gas is preferably supplied for 250seconds or less. However, the present invention is not limited to theabove.

In another aspect of the present invention, there is also provided ahigh power fuel cell system in which a humidified gas and a dry gas areselectively supplied as oxidant to a cathode of a fuel cell, the systemincluding: a stack including a single membrane electrode assembly orincluding at least two membrane electrode assemblies and a separatorinterposed between the membrane electrode assemblies; a detectorconnected to both ends of the stack to measure current or voltage atboth ends of the stack; a controller connected to the detector, thecontroller generating a humidified gas supply signal when the fuel cellstarts operation, then receiving a measured current or voltage valuefrom the detector to generate a dry gas supply signal to increase apower in case the power is constantly maintained or decreased after thehumidified gas is initially supplied, and then alternately generating ahumidified gas supply signal and a dry gas supply signal to maintain theincreased or predetermined power; and an oxidant supplier for receivinga signal of the controller and selectively supplying a dry gas or ahumidified gas according to the signal.

DESCRIPTION OF DRAWINGS

FIG. 1 is a schematic view illustrating the principle for generatingelectricity of a fuel cell.

FIG. 2 is a schematic view illustrating a general configuration of amembrane electrode assembly for a fuel cell.

FIG. 3 is a graph illustrating output voltages, measured at certaincurrent densities (a: 300 mA/cm², b: 500 mA/cm², c: 700 mA/cm², d: 900mA/cm²) after subsequently supplying a humidified gas, a dry gas and ahumidified gas to a cathode while a fuel cell is in operation;

FIG. 4 is a graph illustrating measurement results of output voltagesaccording to an example 1 of the present invention;

FIG. 5 is a schematic view illustrating one example of a high power fuelcell system according to the present invention;

FIG. 6 is a graph illustrating measurement results of output voltagesand increases of the output voltages according to an example 1 of thepresent invention; and

FIG. 7 is a graph illustrating measurement results of output voltagesand increases of the output voltages according to an example 2 of thepresent invention.

BEST MODE

Hereinafter, an electrode for a fuel cell of the present invention willbe described in detail according to its preparing method. Prior to thedescription, it should be understood that the terms used in thespecification and the appended claims should not be construed as limitedto general and dictionary meanings, but interpreted based on themeanings and concepts corresponding to technical aspects of the presentinvention on the basis of the principle that the inventor is allowed todefine terms appropriately for the best explanation.

As mentioned above, inventors found that the power of a fuel cell isgreatly improved when a dry gas is supplied to a cathode of the fuelcell while a humidified gas is supplied as oxidant to the cathode duringa predetermined time. In this regards, FIG. 3 shows a graph exhibiting avoltage measured while supplying a humidified gas with a relativehumidity of about 100% to a cathode of a fuel cell for a certain time,then supplying a dry gas with a relative humidity of about 0%, and thensupplying a humidified gas again (a: 300 mA/cm², b: 500 mA/cm², c: 700mA/cm², d: 900 mA/cm²). Here, it would be understood that the power of afuel cell is increased in case a dry gas is supplied after a humidifiedgas is initially supplied. The present invention discloses a high powerfuel cell system and its operating method, which may maintain a highpower of a fuel cell on the above perception.

Hereinafter, a method of operating a fuel cell according to the presentinvention is explained in detail.

The method of operating a fuel cell according to the present inventionis used for operating a high power fuel cell in which a humidified gasor a dry gas is selectively supplied as oxidant to a cathode of the fuelcell. Here, a humidified gas is firstly supplied to the cathode while apower is maintained or until a power begins to decrease (S1).

As shown in FIG. 3, while a humidified gas is initially supplied, thepower of the fuel cell is not greatly changed. However, as time goes,the power is maintained to a certain level or decreases slightly.

The humidified gas and the dry gas may adopt any oxidant used in theart. For example, the humidified gas and the dry gas may be air oroxygen, but not limitedly.

The humidity of the humidified gas may be selected without anylimitation if moisture may be supplied over a minimal level. Forexample, the humidified gas may have a relative humidity of 70% orabove, but not limitedly. As the relative humidity of the humidified gasis greater, the humidifying effect aimed in the present invention may bemore excellent. For example, the relative humidity of the humidified gasmay be 99.9999%, but not limitedly.

Then, after the humidified gas is supplied, a dry gas is supplied to thecathode so as to obtain a greater power than an average power of thestep S1 (S2).

As shown in FIG. 3, when a dry gas is supplied to the cathode after thehumidified gas is initially supplied, the power of the fuel cell isincreased. In particular, it would be understood that the power isgreatly increased, as current density is greater. It is considered that,as the dry gas is supplied, the flooding phenomenon in the electrode issolved, and moisture is evaporated at a three-phase reaction point suchthat O₂ may more easily reaches the three-phase reaction point, therebyincreasing the power of a fuel cell.

The humidity of the dry gas may be selected without any limitation ifthe flooding of an electrode may be solved. For example, the dry gas mayhave a relative humidity of 20% or less, but not limitedly. As therelative humidity of the dry gas is smaller, the drying effect aimed bythe present invention may be more excellent. For example, the relativehumidity of the dry gas may be 0.0001% at the minimum, but notlimitedly.

Subsequently, after a predetermined power is obtained in the step S2,when the power decreases, a humidified gas is supplied to the cathode tomaintain the predetermined power. After that, when the power decreasesagain, a dry gas is supplied to increase the power such that thepredetermined power may be maintained (S3). The above process isrepeatedly executed.

As shown in FIG. 3, when the time for supplying a dry gas passes, itwould be understood that the power reaches a peak, is kept at the peakfor a while, and then decreases again.

In a region where the power increases and is kept at a certain valuewhile a dry gas is introduced to the cathode, the flooding phenomenon issolved and moisture at the three-phase reaction point is evaporated tocontribute to the increase of power. However, moisture in an ionomer isevaporated together, which seems to decrease the power. As a result,there is found a region where the entire power of the fuel cell isconstant.

After that, if the dry gas is supplied continuously, the floodingphenomenon is entirely eliminated, and moisture in the ionomer isexcessively evaporated, which prohibits transfer of proton through theionomer, so the power starts being deteriorated.

Thus, as shown in FIG. 3, if a humidified gas is supplied secondarily,the shortage of moisture is solved, thereby increasing the power.However, if the humidified gas is supplied continuously, moisture isexcessively supplied, so the power of the fuel cell starts beingdeteriorated.

Thus, the method of operating a fuel cell according to the presentinvention includes the step of controlling an amount of moisture bysupplying a dry gas again to the cathode if the power decreases afterthe secondary humidified gas is supplied. The above procedure iscirculated to supply a humidified gas and a dry gas alternately, therebyproviding a high power. In this way, a power higher than an averagepower of the step (S1), namely an initial power, may be maintained.

Therefore, the point of alternating between a humidified gas and a drygas may be a point when the power of a fuel cell is deteriorated lowerthan a demanded high power.

While operating a fuel cell, any person having ordinary skill in the artwould easily find such an alternating point for supplying a humidifiedgas or a dry gas. For example, a humidified gas may be supplied for 20seconds or less from the point that the humidified gas starts beingsupplied, but not limitedly. If a humidified gas is supplied over 20seconds, flooding may occur. Also, a dry gas may be supplied for 250seconds or less from the point that the dry gas starts being supplied.If the dry gas is supplied over 250 seconds, moisture may beinsufficient in an electrode membrane. The time period for supplying ahumidified gas or a dry gas has no special restriction in its lowestlimit, since it would be sufficient if flooding does not occur or theelectrode membrane is not dried in earnest. For example, a humidifiedgas may be supplied for 1 to 20 seconds, and a dry gas may be suppliedfor 1 to 250 seconds, for example, but not limitedly.

FIGS. 4, 6 and 7 are graphs showing output voltages at certain currentdensity, measured while initially supplying a humidified gas, thensupplying a dry gas to increase a power, and then alternately supplyinga humidified gas and a dry gas again. In FIG. 4, it is well illustratedthat an output voltage is constant in an initial humidified gas supplyregion, then the output voltage is greatly increased in a region wherethe dry gas is supplied, and then the increased output voltage ismaintained in a region (a) where humidified and dry gases arealternately supplied.

Also, referring to FIGS. 6 and 7, in a region where humidified and drygases are alternately supplied after a high power is obtained(corresponding to the region (a) in FIG. 4), namely in a high powerregion, it would be found that the power is repeatedly increased anddecreased based on an average power. As mentioned above, such increaseand decrease of power in the high power region result from repeatedalternate supply of humidified and dry gases. Average power value andhighest and lowest power values in the high power region may bevariously and suitably selected according to the field to which a fuelcell is applied, so they are not specially limited. For example, as foroutput values in the high power region, the lowest power value may be90% of an average power in the high power region, and the highest powervalue may be 110% of the average power in the high power region, but notlimitedly.

In addition, in the operating method of the present invention, ascurrent density is greater, the power is more increased. Thus, a highpower may be more effectively obtained when a fuel cell is operated withcurrent density of 500 mA/cm² or above. Various current densities aredemanded according to the fields to which a fuel cell is applied, so anupper limit of the current density is not specially restricted. Forexample, a fuel cell may be operated with current density of about 1,000mA/cm², and when being applied to a vehicle, a fuel cell may also beoperated with current density of 1,200 mA/cm² to 1,400 mA/cm².

Hereinafter, a high power fuel cell system is explained in detail withreference to the accompanying drawings as one embodiment operated to themethod of the present invention. However, the embodiment described hereand illustrated in the drawings is just one preferred example of thepresent invention and does not represent all spirit of the presentinvention, so it would be understood that there might be variousequivalents and modifications that may be substituted for the presentinvention.

A high power fuel cell system according to one embodiment of the presentinvention is configured such that a humidified gas or a dry gas isselectively supplied as oxidant to a cathode of a fuel cell. The highpower fuel cell system includes a stack including a single membraneelectrode assembly or including at least two membrane electrodeassemblies and a separator interposed between the membrane electrodeassemblies; a detector connected to both ends of the stack to measurecurrent or voltage at both ends of the stack; a controller connected tothe detector to generate a humidified gas supply signal when the fuelcell starts operation, then receiving a measured current or voltagevalue from the detector to generate a dry gas supply signal to increasea power in case the power is constantly maintained or decreased afterthe humidified gas is initially supplied, and then alternatelygenerating a humidified gas supply signal or a dry gas supply signal tomaintain the increased or predetermined power; and an oxidant supplierfor receiving a signal of the controller and selectively supplying a drygas or a humidified gas according to the signal.

FIG. 5 is a schematic view showing a high power fuel cell systemaccording to one embodiment of the present invention. Referring to FIG.5, the high power fuel cell system of this embodiment includes amembrane electrode assembly having an anode 511, a cathode 512 and anelectrolyte membrane 513; gas ports of the fuel cell having an anodeinlet 501, an anode outlet 502, a cathode inlet 503 and a cathode outlet504; a detector having output current and voltage measurement lines 507;a controller 514; and an oxidant supplier having a dry gas line 506, avalve 516, a humidifier 515 and a humidified gas line 505.

The membrane electrode assembly employed in the present invention mayuse any membrane electrode assembly commonly used in the art, as shownin FIG. 2. The membrane electrode assembly for the fuel cell accordingto the present invention includes an electrolyte membrane 201; and ananode and a cathode located at opposite sides of the electrolytemembrane 201. The anode and cathode may include a gas diffusion layer208 and catalyst layers 203 and 205, respectively. The gas diffusionlayer 208 for the fuel cell according to the present invention mayinclude substrates 209 a and 209 b and microporous layers 207 a and 207b formed on one side of the substrates 209 a and 209 b, respectively.

The electrolyte membrane of the present invention separates bothelectrodes and becomes a passage of proton and moisture. The electrolytemembrane employed in the present invention may adopt any electrolytemembrane used in the art, for example any one polymer selected from thegroup consisting of perfluorosulfonic acid polymer, hydrocarbon-basedpolymer, polyimide, polyvinylidene fluoride, polyethersulfone,polyphenylene sulfide, polyphenylene oxide, polyphosphazene,polyethylene naphthalate, polyester, doped polybenzimidazol, polyetherketone, polysulfone, or their acids and bases, but the present inventionis not limited thereto.

The catalyst layer of the present invention gives a place for oxidationreaction and reduction reaction. The catalyst layer exists on the anodeand the cathode, respectively, and it includes a catalyst and a polymerionomer.

The catalyst may employ any catalyst used in the art without limitation.For example, the catalyst may be a metal catalyst or a metal catalyst ona carbon-based support. The metal catalyst may use representativelyplatinum, ruthenium, osmium, platinum-ruthenium alloy, platinum-osmiumalloy, platinum-palladium alloy, platinum-molybdenum alloy,platinum-rhodium alloy and platinum-transition metal alloy, or theirmixtures, but not limitedly.

The carbon-based support may be a carbon-based material, preferably anyone of graphite, carbon black, acetylene black, denka black, ketjenblack, activated carbon, mesoporous carbon, carbon nanotube, carbon nanofiber, carbon nano horn, carbon nano ring, carbon nano wire, fullerene(C60) and Super-P, or their mixtures.

The polymer ionomer employ any one commonly used in the art, for examplerepresentatively a nafion ionomer or a sulfonated polymer such assulfonated polytrifluorostyrene, but not limitedly.

The gas diffusion layer of the present invention plays a role of currentconductive material between the separator and the catalyst layer and itbecomes a passage of gas that is a reactant and water that is a product.Thus, the gas diffusion layer has a porous structure (with a porosity of20 to 90%) such that gas may easily pass through it.

The gas diffusion layer may adopt any gas diffusion layer used in theart, and it may include a conductive substrate selected from the groupconsisting of carbon paper, carbon cloth and carbon felt. The gasdiffusion layer may further include a microporous layer formed on oneside of the conductive substrate, and the microporous layer may be madeof a carbon-based material or a fluorine-based resin.

The carbon-based material may be any one selected from the groupconsisting of graphite, carbon black, acetylene black, denka black,ketjen black, activated carbon, mesoporous carbon, carbon nanotube,carbon nano fiber, carbon nano horn, carbon nano ring, carbon nano wire,fullerene (C60) and Super-P, or their mixtures, but the presentinvention is not limited thereto.

The fluorine-based resin may be any one selected from the groupconsisting of polytetrafluoroethylene, polyvinylidene fluoride (PVdF),polyvinyl alcohol, cellulose acetate, polyvinylidenefluoride-hexafluoropropylene (PVdF-HFP) copolymer and styrene-butadienerubber (SBR), or their mixtures, but the present invention is notlimited thereto.

The gas diffusion layer may have a suitable thickness as necessary, forexample 100 to 400 μm, but not limitedly. If the gas diffusion layer hastoo small thickness, an electric contact resistance between the catalystlayer and the separator is increased, and the gas diffusion layer maynot have so sufficient force to ensure compression. If the thickness istoo great, the reactant, gas, may not easily move. Thus, the thicknessof the gas diffusion layer should be maintained in a suitable level.

At this time, the catalyst layer is formed between the electrolytemembrane and the microporous layer of the gas diffusion layer.

The separator plays a role of preventing membrane electrode assembliesfrom being electrically connected to each other and transferring fueland oxidant supplied from the outside to the membrane electrodeassemblies. The separator may adopt any one commonly used in the art.For example, graphite and stainless steel are representative, but notlimited thereto.

The fuel introduced into the anode inlet 501 may use hydrogen orhydrocarbon fuel in a gaseous or liquid state, and the hydrocarbon fuelmay be methanol, ethanol, propanol, butanol or natural gas.

The oxidant introduced to the cathode inlet 503 may representatively useoxygen or air, and the oxidant is introduced through the humidified gasline 505 or the dry gas line 506.

In the fuel cell system of the present invention, the detector 507 isconnected to both ends of the stack to measure current and voltage whilethe fuel cell is operated. There are various devices electricallyconnected to both ends of a fuel cell to measure current and voltage,and they may be used as a detector without any limitation.

In the fuel cell system of the present invention, the controller 514compares a predetermined power or a maximum power set by the initialsupply of dry gas with a power transmitted from the detector 507 todetermine whether to supply a humidified gas or a dry gas, and thentransmits a signal to the oxidant supplier.

In detail, when the fuel cell is in operation, the controller transmitsa humidified gas supply signal to the oxidant supplier at an initialstage while a power is maintained constantly or until a power begins todecrease. Then, the controller transmits a dry gas supply signal to theoxidant supplier to increase the power. At this time, the dry gas supplysignal is continuously transmitted while the power is increased ormaintained in the increased state or until the power begins to decreasebelow a predetermined value with reference to the power transmitted fromthe detector 507.

Subsequently, if the power transmitted from the detector 507 isdecreased below the increased power or a predetermined power, thecontroller transmits a humidified gas supply signal again. Thecontroller keeps checking the power transmitted from the detector 507,and then if the power is decreased below the increased power or apredetermined power again after the humidified gas supply signal istransmitted, the controller transmits a dry gas supply signal. Afterthat, the controller alternately transmits humidified gas supply signalsand dry gas supply signals to the oxidant supplier as mentioned abovesuch that the power transmitted from the detector 507 is not decreasedbelow the increased power or the predetermined power.

In other words, the controller 514 determines a power greater than anaverage power transmitted from the detector 507 while the initialhumidified gas is supplied as a lowest limit, and then sends humidifiedgas supply signals and dry gas supply signals to the oxidant suppliersuch that a power is not decreased below the predetermined power.

The controller 514 may be implemented in various ways well known in theart. For example, the controller ay be a program executing the aboveprocedure, an electric circuit or a microprocessor performing such aprogram, or the like, but not limitedly.

In the fuel cell system of the present invention, the oxidant supplierreceives signals from the controller 514 to supply humidified gas or drygas to the cathode electrode as an oxidant. Humidified gas and dry gasmay be selectively supplied in various ways commonly used in the artwithout any special limitation.

For example, as shown in FIG. 5, the oxidant supplier employed in thepresent invention may include the dry gas line 506 connected to thecathode inlet 503 of a fuel cell; a three-directional valve 516 providedon the dry gas line; and a humidified gas line 505 diverged from thethree-directional valve and connected to an oxidant input portion of thefuel cell and having the humidifier 515 thereon, but not limitedly.Here, the oxidant supplier switches the three-direction valve toalternately supply humidified gas and dry gas according to signals fromthe controller 514. In detail, if a dry gas supply signal is receivedfrom the controller 514, the three-directional valve closes thehumidified gas line and opens the dry gas line to supply the dy gasline. On the contrary, if a humidified gas supply signal is received,the three-directional valve closes the dry gas line and opens thehumidified gas line to supply the humidified gas.

Humidity of the humidified gas supplied from the oxidant supplier may beselected without any limitation if an amount of supplied moisture is notless than a minimal level necessary to an electrode. For example, arelative humidity of the humidified gas may be 70% or above, but notlimitedly. As the relative humidity of the humidified gas is greater, ahumidifying effect aimed by the present invention may be more excellent.For example, the relative humidity of the humidified gas may be99.9999%, but not limitedly.

Humidity of the dry gas supplied from the oxidant supplier may beselected without any limitation if flooding of an electrode may besolved. For example, a relative humidity of the dry gas may be 20% orless, but not limitedly. As the relative humidity of the dry gas issmaller, a drying effect aimed by the present invention may be moreexcellent. For example, the relative humidity of the dry gas may be0.0001% as a minimal value, but not limitedly.

Kinds and locations of he dry gas line, the humidified gas line, thevalve and the humidifier shown in FIG. 5 are just one example of thepresent invention, and it should be understood that their locations andconfigurations may be changed in various ways.

MODE FOR INVENTION

Hereinafter, the present invention is explained in more detail usingembodiments. However, the following embodiments may be modified invarious ways, and the present invention should not be interpreted asbeing limited thereto. The following embodiments are just given forpersons having ordinary skill in the art to understand the presentinvention in a better way.

Embodiment 1

Catalyst layers using platinum catalysts were formed on both surfaces ofan electrolyte membrane (Nafion 112, Dupont), and a gas diffusion layermade of graphite fiber was adhered thereto to make a unit cell.

The unit cell prepared as above was operated at a cell temperature of70° C. under a hydrogen/air condition, during which a voltage change at900 mA/cm² was measured. At this time, gas stoichiometries were 1.3(anode gas) and 2.0 (cathode gas).

From starting the operation till 63 seconds, a humidified gas with arelative humidity of 100% (±0.5) was supplied to a cathode, and afterthat, a dry gas with a relative humidity of 0% (±0.5) was supplied tothe cathode till 132 seconds. After the supply of dry gas till 528seconds, humidified gas and dry gas were alternately supplied wheneveran output voltage decreases while increasing, thereby maintaining thepower. After 528 seconds, only humidified gas was supplied, and then theoperation was stopped at 850 seconds.

While the fuel cell is operated, the change of output voltage wasobserved. The results are shown in FIG. 6.

Embodiment 2

The change of voltage at 1 A/cm² was measured. From starting theoperation of a fuel cell till 83 seconds, a humidified gas was suppliedto a cathode, and after that, a dry gas was supplied till 209 seconds.After that till 705 seconds, humidified gas and dry gas were alternatelysupplied whenever an output voltage decreases while increasing. After705 seconds, only humidified gas was supplied, and then the operationwas stopped at 1060 seconds.

While the fuel cell is operated, the change of output voltage wasobserved. The results are shown in FIG. 7.

Referring to FIGS. 6 and 7, the fuel cell system of the presentinvention may continuously maintain a high power, differently from thecase that a gas with a constant humidity is supplied to a cathodeelectrode as shown in FIG. 3. In addition, it would be found that anaverage power was increased by about 16.5% and 17.6%, respectively,while an increased power is maintained after a dry gas is supplied, incomparison to an average power when a humidified gas is initiallysupplied.

INDUSTRIAL APPLICABILITY

In the method of operating a fuel cell according to the presentinvention, it is possible to obtain a great power in an effective wayeven in a state that a great power is demanded temporarily. In addition,the method of the present invention allows to operate a fuel cell withgreater power than a conventional fuel cell even using the same amountof fuel or oxidant.

Also, the fuel cell system of the present invention may give a greaterpower than a conventional fuel cell. The fuel cell operating method andthe fuel cell system disclosed above may be applied to all kinds ofindustrial fields where fuel cells are used, particularly suitably forvehicles and home heating equipment, which demand great power.

1. A method of operating a fuel cell with high power, in which ahumidified gas and a dry gas are selectively supplied as oxidant to acathode of the fuel cell, the method comprising: (S1) supplying ahumidified gas while a power is constantly maintained or until the powerbegins to decrease; (S2) after supplying the humidified gas, supplying adry gas to obtain a greater power than an average power of the step(S1); and (S3) after obtaining a predetermined power in the step (S2),repeatedly supplying a humidified gas in case the power decreases andsupplying a dry gas in case the power decreases again afterwards,thereby increasing the power such that the predetermined power ismaintained.
 2. The method of operating a fuel cell with high poweraccording to claim 1, wherein, in the steps (S1) and (S3), thehumidified gas is supplied for 20 seconds or less.
 3. The method ofoperating a fuel cell with high power according to claim 1, wherein, inthe steps (S2) and (S3), the dry gas is supplied for 250 seconds orless.
 4. The method of operating a fuel cell with high power accordingto claim 1, wherein the fuel cell is operated with current density of500 mA/cm² or above.
 5. The method of operating a fuel cell with highpower according to claim 1, wherein an average power in the step (S3) isgreater than the average power in the step (S1).
 6. The method ofoperating a fuel cell with high power according to claim 1, wherein apower value in the step (S3) is according to the following Math FIG. 1:Math FIG. 1 90% of an average power in the step (S3) ≦the power value inthe step (S3) ≦110% of the average power in the step (S3).
 7. The methodof operating a fuel cell with high power according to claim 1, whereinthe humidified gas has a relative humidity of 70% or above.
 8. Themethod of operating a fuel cell with high power according to claim 1,wherein the dry gas has a relative humidity of 20% or below.
 9. A highpower fuel cell system in which a humidified gas and a dry gas areselectively supplied as oxidant to a cathode of a fuel cell, the systemcomprising: a stack including a single membrane electrode assembly orincluding at least two membrane electrode assemblies and a separatorinterposed between the membrane electrode assemblies; a detectorconnected to both ends of the stack to measure current or voltage atboth ends of the stack; a controller connected to the detector, thecontroller generating a humidified gas supply signal when the fuel cellstarts operation, then receiving a measured current or voltage valuefrom the detector to generate a dry gas supply signal to increase apower in case the power is constantly maintained or decreased after thehumidified gas is initially supplied, and then alternately generating ahumidified gas supply signal and a dry gas supply signal to maintain theincreased or predetermined power; and an oxidant supplier for receivinga signal of the controller and selectively supplying a dry gas or ahumidified gas according to the signal.
 10. The high power fuel cellsystem according to claim 9, wherein the humidified gas is supplied for20 seconds or less.
 11. The high power fuel cell system according toclaim 9, wherein the dry gas is supplied for 250 seconds or less. 12.The high power fuel cell system according to claim 9, wherein the fuelcell is operated with current density of 500 mA/cm² or above.
 13. Thehigh power fuel cell system according to claim 9, wherein an averagepower while the humidified gas is initially supplied as oxidant issmaller than an average power while the dry gas and the humidified gasare supplied alternately afterwards.
 14. The high power fuel cell systemaccording to claim 9, wherein, in a high power region where an increasedpower is maintained after the humidified gas is initially supplied, apower value is according to the following Math FIG. 2: Math FIG. 2 90%of an average power in the high power region≦the power value in the highpower region ≦110% of the average power in the high power region. 15.The high power fuel cell system according to claim 9, wherein thehumidified gas has a relative humidity of 70% or above.
 16. The highpower fuel cell system according to claim 9, wherein the dry gas has arelative humidity of 20% or below.